Silicon carbide
Edward G. Acheson
Almost at the same time, Edward G. Acheson (United States) designed a method to manufacture from clay and coal coke a material that could replace diamond as abrasive and cutting material (Acheson method); he gave the product obtained (silicon carbide) the name of carborundum. In 1894 he created the company Carborundum Co to market his discovery.
Industrial process
The industrial process performed by Navarro SiC for the production of silicon carbide uses Acheson method, based on the following chemical reaction:
SiO2 + 3·C -> SiC + 2·CO
A mixture of high purity sand or quartz and petroleum coke chemically react in Acheson furnace at temperatures up to 2,500 °C. The energy needed for the reaction is produced by the resistive heating of a graphite core connected to two electrodes at the ends of the furnace..
The reaction proceeds for about 36 hours, with the formation of ß-SiC (cubic silicon carbide) from 1,400 °C and the recrystallization and formation of α-SiC (hexagonal silicon carbide ) from 1.800 °C.
The reaction proceeds for about 36 hours, with the formation of ß-SiC (cubic silicon carbide) from 1,400 °C and the recrystallization and formation of α-SiC (hexagonal silicon carbide ) from 1.800 °C.
SiC reaction furnace |
α-SiC (hexagonal silicon carbide) |
Silicon carbide develops in the furnace as a solid cylindrical ingot around the graphite core, with concentric layers that decrease their SiC content with the distance from the core. It can be black or green depending on the composition of the raw materials used.
Characteristics of silicon carbide
Silicon carbide has an extreme hardness, second only to diamond and a few synthetic compounds. It is also highly resistant to heat. These properties make silicon carbide an irreplaceable material for abrasive and refractory applications.
Property | Test | Value |
Physical properties |
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Color | black, dark grey, green | |
Hardness | UNE EN ISO 4545-1:2006 | 2,500 - 2,800 MPa |
Density | ASTM C20 | 3.21 g·cm-3 |
Moisture absorption | ASTM C373 | 0.0 % |
Refraction Index n0 | 2.65 | |
Mechanical properties |
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Resistance to compression | ASTM C773 | 1,725 - 2,500 MPa |
Resistance to traction | ACMA Test #4 | 310 MPa |
Young's elasticity modulus | ASTM C848 | 420 - 476 GPa |
Flexural rupture modulus | ASTM F417 | 324 - 450 MPa |
Toughness to fracture | Three-point flexural test | 2.3 - 4.0 MPa·m1/2 |
Thermal properties |
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Thermal stability | 1,400 ºC al aire | |
Resistance to thermal stress | Tempering | 350 - 500 ºC |
Thermal conductivity (298 K) | ASTM C408 | 41 - 90 W·m-1·K-1 |
Linear thermal expansion | ASTM C372 | 4.7 - 5.1·10-6 K-1 |
Average specific heat | ASTM C351 | 0.15 - 0.22 cal·g-1·K-1 |
Electrical properties |
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Dielectric constant | ASTM D150 | 10.2 MHz |
Electrical resistivity | ASTM D1829 | 108 W·cm |